Object[Protocol, SupercriticalFluidChromatography]
A protocol describing the separation of materials using supercritical CO2 fluid chromatography (SFC).
Organizational Information
Name
Name of this Object.
Format: Single
Class: String
Programmatic Pattern: _String
Pattern Description: A string.
ID
ID of this Object.
Format: Single
Class: String
Programmatic Pattern: _String
Pattern Description: The ID of this object.
Object
Object of this Object.
Format: Single
Class: Expression
Programmatic Pattern: Object[Protocol, SupercriticalFluidChromatography, _String]
Pattern Description: The object reference of this object.
Type
Type of this Object.
Format: Single
Class: Expression
Programmatic Pattern: Object[Protocol, SupercriticalFluidChromatography]
Pattern Description: Object[Protocol, SupercriticalFluidChromatography]
Notebook
Notebook this object belongs to.
Format: Single
Class: Link
Programmatic Pattern: _Link
Pattern Description: An object of that matches ObjectP[Object[LaboratoryNotebook]].
Relation: Object[LaboratoryNotebook][Objects]
Author
The investigator who created this protocol.
Format: Single
Class: Link
Programmatic Pattern: _Link
Relation: Object[User][ProtocolsAuthored]
General
DateConfirmed
The date on which the protocol first entered processing or a backlog.
Format: Single
Class: Date
Programmatic Pattern: _?DateObjectQ
DateEnqueued
The date on which the protocol was accepted and added to the queue.
Format: Single
Class: Date
Programmatic Pattern: _?DateObjectQ
DateStarted
The date on which the protocol moved from the front of the queue to begin running in the lab.
Format: Single
Class: Date
Programmatic Pattern: _?DateObjectQ
DateCompleted
The date on which the last step of this protocol's execution was finished.
Format: Single
Class: Date
Programmatic Pattern: _?DateObjectQ
DateCanceled
The date on which the protocol was canceled and removed from the queue.
Format: Single
Class: Date
Programmatic Pattern: _?DateObjectQ
Script
The script that created this protocol.
Format: Single
Class: Link
Programmatic Pattern: _Link
Relation: Object[Notebook][Protocols]
SubprotocolScripts
All scripts generated by this protocol as a list of subprotocols.
Format: Multiple
Class: Link
Programmatic Pattern: _Link
Relation: Object[Notebook, Script][ParentProtocol]
Site
The ECL site at which this protocol was executed.
Format: Single
Class: Link
Programmatic Pattern: _Link
Relation: Object[Container, Site]
SamplesIn
Input samples for this analytical or preparative experiment.
Format: Multiple
Class: Link
Programmatic Pattern: _Link
ContainersIn
Any containers containing this protocols' SamplesIn.
Format: Multiple
Class: Link
Programmatic Pattern: _Link
NumberOfReplicates
Indicates the number of times the experiment is repeated with identical parameters.
Format: Single
Class: Integer
Programmatic Pattern: GreaterP[0, 1]
Status
The current status of the protocol.
Format: Single
Class: Expression
Programmatic Pattern: ProtocolStatusP
CheckpointProgress
A listing of all the checkpoints passed in the execution of this protocol.
Format: Multiple
[[1]] Name
Header: Name
Class: String
Programmatic Pattern: _String
[[2]] Start Time
Header: Start Time
Class: Date
Programmatic Pattern: _?DateObjectQ
[[3]] End Time
Header: End Time
Class: Date
Programmatic Pattern: _?DateObjectQ|Null
SubprotocolDescription
A short title indicating what this subprotocol accomplishes.
Format: Single
Class: String
Programmatic Pattern: _String
BatchedUnitOperations
The individual batches of the protocol, as they will be executed in the lab.
Format: Multiple
Class: Link
Programmatic Pattern: _Link
Relation: Object[UnitOperation][Protocol]
ReplacementProtocol
If this protocol was aborted due to technical reasons, links to the replacement protocol run in its place.
Format: Single
Class: Link
Programmatic Pattern: _Link
Sterile
Indicates if the protocol is performed in a sterile environment.
Format: Single
Class: Expression
Programmatic Pattern: BooleanP
LiquidHandlingLog
The instrumentation trace file that monitored and recorded the execution of this robotic liquid handling.
Format: Single
Class: Link
Programmatic Pattern: _Link
Relation: Object[EmeraldCloudFile]
PooledSamplesIn
The members of SamplesIn gathered into the pools that are mixed in each AliquotContainer.
Format: Multiple
Class: Expression
Programmatic Pattern: {ObjectReferenceP[Object[Sample]]..}
NestedIndexMatchingSamplesIn
The members of SamplesIn gathered into the pools that are mixed in each AliquotContainer.
Format: Multiple
Class: Expression
Programmatic Pattern: {ObjectReferenceP[Object[Sample]]..}
InitialNitrogenPressure
The pressure data of the nitrogen gas source before starting the experiment.
Format: Single
Class: Link
Programmatic Pattern: _Link
Relation: Object[Data][Protocol]
NitrogenPressureLog
The pressure log for the nitrogen gas source for the relevant section of the facility.
Format: Single
Class: Link
Programmatic Pattern: _Link
Relation: Object[Data][Protocol]
InitialCO2Pressure
The pressure data of the CO2 gas source before starting the experiment.
Format: Single
Class: Link
Programmatic Pattern: _Link
Relation: Object[Data][Protocol]
CO2PressureLog
The pressure log for the CO2 gas source for the relevant section of the facility.
Format: Single
Class: Link
Programmatic Pattern: _Link
Relation: Object[Data][Protocol]
InitialArgonPressure
The pressure data of the argon gas source before starting the experiment.
Format: Single
Class: Link
Programmatic Pattern: _Link
Relation: Object[Data][Protocol]
HoldOrder
Indicates if the queue position of this protocol should be strictly enforced, regardless of the available resources in the lab.
Format: Single
Class: Boolean
Programmatic Pattern: BooleanP
Priority
Indicates if this protocol should be prioritized to start at the given StartDate, have dedicated operation for its entirety, and not be interrupted by other protocols.
Format: Single
Class: Boolean
Programmatic Pattern: BooleanP
StartDate
The date at which this protocol should be prioritized to start.
Format: Single
Class: Date
Programmatic Pattern: _?DateObjectQ
Branch
The git branch that this protocol should be run on.
Format: Single
Class: String
Programmatic Pattern: _String
Instrument
The device containing a pump, column oven, and detector(s) that executes this experiment.
Format: Single
Class: Link
Programmatic Pattern: _Link
Scale
Indicates if the SFC is intended to separate material (Preparative) and therefore collect fractions and/or analyze properties of the material (Analytical).
Format: Single
Class: Expression
Programmatic Pattern: PurificationScaleP
SeparationMode
The type of chromatographic separation that categorizes the mobile and stationary phase used, ideally for optimal sample separation and resolution.
Format: Single
Class: Expression
Programmatic Pattern: SeparationModeP
Detectors
Indicates the types of measurements performed for the experiment and available on the Instrument.
Format: Multiple
Class: Expression
Programmatic Pattern: ChromatographyDetectorTypeP
AcquisitionMode
For experiments with MassSpectrometry available, the type of acquisition being performed in this protocol. MS mode measures the masses of the intact analytes, whereas MSMS measures the masses of the analytes fragmented by collision-induced dissociation.
Format: Single
Class: Expression
Programmatic Pattern: AcquisitionModeP
MassAnalyzer
For experiments with MassSpectrometry available, the type of the component of the mass spectrometer that performs ion separation based on m/z (mass-to-charge ratio). SingleQuadrupole selects ions individually for measurement.
Format: Single
Class: Expression
Programmatic Pattern: MassAnalyzerTypeP
IonSource
For experiments with MassSpectrometry available, the type of ionization used to create gas-phase ions from the molecules in the sample. Electrospray ionization (ESI) produces ions using an electrospray in which a high voltage is applied to a liquid to create an aerosol, and gas-phase ions are formed from the fine spray of charged droplets as a result of solvent evaporation and Coulomb fission.
Format: Single
Class: Expression
Programmatic Pattern: IonSourceP
PurgeWasteContainerA
The container used to hold waste from air bubble removal procedures for buffer lines. It is also used to hold waste from rinsing plumbing connections.
Format: Single
Class: Link
Programmatic Pattern: _Link
PurgeWasteContainerB
The container used to hold waste from air bubble removal procedures for buffer lines.
Format: Single
Class: Link
Programmatic Pattern: _Link
CosolventA
The solvent connected to position A, the flow of which is directed by GradientA compositions.
Format: Single
Class: Link
Programmatic Pattern: _Link
CosolventB
The solvent connected to position B, the flow of which is directed by GradientB compositions.
Format: Single
Class: Link
Programmatic Pattern: _Link
CosolventC
The solvent connected to position C, the flow of which is directed by GradientC compositions.
Format: Single
Class: Link
Programmatic Pattern: _Link
CosolventD
The solvent connected to position D, the flow of which is directed by GradientD compositions.
Format: Single
Class: Link
Programmatic Pattern: _Link
MakeupSolvent
The solution pumped and supplementing the column effluent on entry to the mass spectrometer.
Format: Single
Class: Link
Programmatic Pattern: _Link
CosolventACap
The cap used to aspirate CosolventA during this protocol.
Format: Single
Class: Link
Programmatic Pattern: _Link
CosolventBCap
The cap used to aspirate CosolventB during this protocol.
Format: Single
Class: Link
Programmatic Pattern: _Link
CosolventCCap
The cap used to aspirate CosolventC during this protocol.
Format: Single
Class: Link
Programmatic Pattern: _Link
CosolventDCap
The cap used to aspirate CosolventD during this protocol.
Format: Single
Class: Link
Programmatic Pattern: _Link
MakeupSolventCap
The cap used to aspirate MakeupSolvent during this protocol.
Format: Single
Class: Link
Programmatic Pattern: _Link
InitialCosolventAVolume
The volume of CosolventA immediately before the experiment was started.
Format: Single
Class: Real
Unit: 1 liter
Programmatic Pattern: GreaterEqualP[0 Liter]
InitialCosolventBVolume
The volume of CosolventB immediately before the experiment was started.
Format: Single
Class: Real
Unit: 1 liter
Programmatic Pattern: GreaterEqualP[0 Liter]
InitialCosolventCVolume
The volume of CosolventC immediately before the experiment was started.
Format: Single
Class: Real
Unit: 1 liter
Programmatic Pattern: GreaterEqualP[0 Liter]
InitialCosolventDVolume
The volume of CosolventD immediately before the experiment was started.
Format: Single
Class: Real
Unit: 1 liter
Programmatic Pattern: GreaterEqualP[0 Liter]
InitialMakeupSolventVolume
The volume of MakeupSolvent immediately before the experiment was started.
Format: Single
Class: Real
Unit: 1 liter
Programmatic Pattern: GreaterEqualP[0 Liter]
InitialCosolventAAppearance
An image of CosolventA taken immediately before the experiment was started.
Format: Single
Class: Link
Programmatic Pattern: _Link
Relation: Object[EmeraldCloudFile]
InitialCosolventBAppearance
An image of CosolventB taken immediately before the experiment was started.
Format: Single
Class: Link
Programmatic Pattern: _Link
Relation: Object[EmeraldCloudFile]
InitialCosolventCAppearance
An image of CosolventC taken immediately before the experiment was started.
Format: Single
Class: Link
Programmatic Pattern: _Link
Relation: Object[EmeraldCloudFile]
InitialCosolventDAppearance
An image of CosolventD taken immediately before the experiment was started.
Format: Single
Class: Link
Programmatic Pattern: _Link
Relation: Object[EmeraldCloudFile]
InitialMakeupSolvent Appearance
An image of MakeupSolvent taken immediately before the experiment was started.
Format: Single
Class: Link
Programmatic Pattern: _Link
Relation: Object[EmeraldCloudFile]
MaxAcceleration
The maximum rate at which it's safe to increase the flow rate for the column and instrument during the run.
Format: Single
Class: Real
Unit: 1 milliliter per minute squared
Programmatic Pattern: 0 Milli Liter
-------------
Minute
Hold[GreaterEqualP[-------------]]
Minute
InjectionTable
The sequence of samples injected for a given experiment run including for ColumnPrime, SamplesIn, Standards, Blanks, and ColumnFlush.
Format: Multiple
[Type]
Header: Type
Class: Expression
[Sample]
Header: Sample
Class: Link
[InjectionVolume]
Header: InjectionVolume
Class: Real
Unit: 1 microliter
[Column]
Header: Column
Class: Link
[Gradient]
Header: Gradient
Class: Link
Relation: Object[Method]
[DilutionFactor]
Header: DilutionFactor
Class: Real
[ColumnTemperature]
Header: ColumnTemperature
Class: Real
Unit: 1 degree Celsius
[Data]
Header: Data
Class: Link
Relation: Object[Data]
Replicate Experiments
Template
The protocol whose option selections should be selected as the default options for this protocol.
Format: Single
Class: Link
Programmatic Pattern: _Link
Relation: Object[Protocol][ProtocolsTemplated]
ProtocolsTemplated
Protocols which were generated using this protocol's options as a starting point for its option defaults.
Format: Multiple
Class: Link
Programmatic Pattern: _Link
Relation: Object[Protocol][Template]
Sample Preparation
PreparatoryUnitOperations
A list of transfers, consolidations, aliquots, mixes and dilutions that will be performed in the order listed to prepare samples for the experiment.
Format: Multiple
Class: Expression
Programmatic Pattern: _ | _
PreparatoryPrimitives
A list of transfers, consolidations, aliquots, mixes and dilutions that will be performed in the order listed to prepare samples for the experiment.
Format: Multiple
Class: Expression
Programmatic Pattern: _ | _
VolumeCheckSamplePrep
Indicates if any liquid samples prepared by using the PreparatoryUnitOperations option should have their volumes measured and updated before running the experiment.
Format: Single
Class: Expression
Programmatic Pattern: BooleanP
IncubateSamplePreparation
For each member of SamplesIn, parameters describing how the input samples should be heated prior to any aliquoting or the start of the experiment.
Format: Multiple
[Incubate]
Header: Incubate
Class: Boolean
[IncubationTemperature]
Header: IncubationTemperature
Class: Real
Unit: 1 degree Celsius
[IncubationTime]
Header: IncubationTime
Class: Real
Unit: 1 second
[Mix]
Header: Mix
Class: Boolean
[MixType]
Header: MixType
Class: Expression
[MixUntilDissolved]
Header: MixUntilDissolved
Class: Boolean
[MaxIncubationTime]
Header: MaxIncubationTime
Class: Real
Unit: 1 second
[IncubationInstrument]
Header: IncubationInstrument
Class: Link
[AnnealingTime]
Header: AnnealingTime
Class: Real
Unit: 1 second
[IncubateAliquotContainer]
Header: IncubateAliquotContainer
Class: Expression
[IncubateAliquot]
Header: IncubateAliquot
Class: Real
Unit: 1 liter
[IncubateAliquotDestinationWell]
Header: IncubateAliquotDestinationWell
Class: Expression
CentrifugeSamplePreparation
For each member of SamplesIn, parameters describing how the input samples should be spun down prior to any aliquoting or the start of the experiment.
Format: Multiple
[Centrifuge]
Header: Centrifuge
Class: Boolean
[CentrifugeInstrument]
Header: CentrifugeInstrument
Class: Link
[CentrifugeIntensity]
Header: CentrifugeIntensity
Class: VariableUnit
[CentrifugeTime]
Header: CentrifugeTime
Class: Real
Unit: 1 minute
[CentrifugeTemperature]
Header: CentrifugeTemperature
Class: Real
Unit: 1 degree Celsius
[CentrifugeAliquotContainer]
Header: CentrifugeAliquotContainer
Class: Expression
[CentrifugeAliquot]
Header: CentrifugeAliquot
Class: Real
Unit: 1 liter
[CentrifugeAliquotDestinationWell]
Header: CentrifugeAliquotDestinationWell
Class: Expression
FilterSamplePreparation
For each member of SamplesIn, parameters describing how particulates should be separated from the input samples prior to any aliquoting or the start of the experiment.
Format: Multiple
[Filtration]
Header: Filtration
Class: Boolean
[FiltrationType]
Header: FiltrationType
Class: Expression
[Filter]
Header: Filter
Class: Link
Relation: Object[Container] | Model[Container] | Object[Sample] | Model[Sample] | Object[Item] | Model[Item]
[FilterMaterial]
Header: FilterMaterial
Class: Expression
[FilterPoreSize]
Header: FilterPoreSize
Class: Real
Unit: 1 micrometer
[FilterContainerOut]
Header: FilterContainerOut
Class: Expression
[FilterInstrument]
Header: FilterInstrument
Class: Link
Relation: Model[Instrument, FilterBlock] | Object[Instrument, FilterBlock] | Model[Instrument, PeristalticPump] | Object[Instrument, PeristalticPump] | Model[Instrument, VacuumPump] | Object[Instrument, VacuumPump] | Model[Instrument, Centrifuge] | Object[Instrument, Centrifuge] | Model[Instrument, SyringePump] | Object[Instrument, SyringePump]
[FilterSyringe]
Header: FilterSyringe
Class: Link
[FilterHousing]
Header: FilterHousing
Class: Link
[FilterIntensity]
Header: FilterIntensity
Class: VariableUnit
[FilterTime]
Header: FilterTime
Class: Real
Unit: 1 minute
[FilterTemperature]
Header: FilterTemperature
Class: Real
Unit: 1 degree Celsius
[FilterSterile]
Header: FilterSterile
Class: Boolean
[FilterAliquotContainer]
Header: FilterAliquotContainer
Class: Expression
[FilterAliquot]
Header: FilterAliquot
Class: Real
Unit: 1 liter
[PrefilterMaterial]
Header: PrefilterMaterial
Class: Expression
[PrefilterPoreSize]
Header: PrefilterPoreSize
Class: Real
Unit: 1 micrometer
[FilterAliquotDestinationWell]
Header: FilterAliquotDestinationWell
Class: Expression
SamplePreparationProtocols
Protocols used to mix, centrifuge, incubate, and filter the SamplesIn prior to starting the experiment.
Format: Multiple
Class: Link
Programmatic Pattern: _Link
PooledIncubateSample Preparation
For each member of PooledSamplesIn, parameters describing how the pooled samples should be incubated after aliquoting but prior to the start of the experiment.
Format: Multiple
[Incubate]
Header: Incubate
Class: Boolean
[IncubationTemperature]
Header: IncubationTemperature
Class: Real
Unit: 1 degree Celsius
[IncubationTime]
Header: IncubationTime
Class: Real
Unit: 1 second
[Mix]
Header: Mix
Class: Boolean
[MixType]
Header: MixType
Class: Expression
[MixUntilDissolved]
Header: MixUntilDissolved
Class: Boolean
[MaxIncubationTime]
Header: MaxIncubationTime
Class: Real
Unit: 1 second
[IncubationInstrument]
Header: IncubationInstrument
Class: Link
[AnnealingTime]
Header: AnnealingTime
Class: Real
Unit: 1 second
[IncubateAliquotContainer]
Header: IncubateAliquotContainer
Class: Expression
[IncubateAliquot]
Header: IncubateAliquot
Class: Real
Unit: 1 liter
[IncubateAliquotDestinationWell]
Header: IncubateAliquotDestinationWell
Class: Expression
NestedIndexMatchingIncubate SamplePreparation
For each member of NestedIndexMatchingSamplesIn, parameters describing how the pooled samples should be incubated after aliquoting but prior to the start of the experiment.
Format: Multiple
[Incubate]
Header: Incubate
Class: Boolean
[IncubationTemperature]
Header: IncubationTemperature
Class: Real
Unit: 1 degree Celsius
[IncubationTime]
Header: IncubationTime
Class: Real
Unit: 1 second
[Mix]
Header: Mix
Class: Boolean
[MixType]
Header: MixType
Class: Expression
[MixUntilDissolved]
Header: MixUntilDissolved
Class: Boolean
[MaxIncubationTime]
Header: MaxIncubationTime
Class: Real
Unit: 1 second
[IncubationInstrument]
Header: IncubationInstrument
Class: Link
[AnnealingTime]
Header: AnnealingTime
Class: Real
Unit: 1 second
[IncubateAliquotContainer]
Header: IncubateAliquotContainer
Class: Expression
[IncubateAliquot]
Header: IncubateAliquot
Class: Real
Unit: 1 liter
[IncubateAliquotDestinationWell]
Header: IncubateAliquotDestinationWell
Class: Expression
PooledCentrifugeSample Preparation
For each member of PooledSamplesIn, parameters describing how the pooled samples should be centrifuge after aliquoting and pooled mixing but prior to the start of the experiment.
Format: Multiple
[Centrifuge]
Header: Centrifuge
Class: Boolean
[CentrifugeInstrument]
Header: CentrifugeInstrument
Class: Link
[CentrifugeIntensity]
Header: CentrifugeIntensity
Class: VariableUnit
[CentrifugeTime]
Header: CentrifugeTime
Class: Real
Unit: 1 minute
[CentrifugeTemperature]
Header: CentrifugeTemperature
Class: Real
Unit: 1 degree Celsius
[CentrifugeAliquotContainer]
Header: CentrifugeAliquotContainer
Class: Expression
[CentrifugeAliquot]
Header: CentrifugeAliquot
Class: Real
Unit: 1 liter
[CentrifugeAliquotDestinationWell]
Header: CentrifugeAliquotDestinationWell
Class: Expression
NestedIndexMatchingCentrifuge SamplePreparation
For each member of PooledSamplesIn, parameters describing how the pooled samples should be centrifuge after aliquoting and pooled mixing but prior to the start of the experiment.
Format: Multiple
[Centrifuge]
Header: Centrifuge
Class: Boolean
[CentrifugeInstrument]
Header: CentrifugeInstrument
Class: Link
[CentrifugeIntensity]
Header: CentrifugeIntensity
Class: VariableUnit
[CentrifugeTime]
Header: CentrifugeTime
Class: Real
Unit: 1 minute
[CentrifugeTemperature]
Header: CentrifugeTemperature
Class: Real
Unit: 1 degree Celsius
[CentrifugeAliquotContainer]
Header: CentrifugeAliquotContainer
Class: Expression
[CentrifugeAliquot]
Header: CentrifugeAliquot
Class: Real
Unit: 1 liter
[CentrifugeAliquotDestinationWell]
Header: CentrifugeAliquotDestinationWell
Class: Expression
FilteredSamples
Samples corresponding to filtered eluents of SamplesIn generated during sample preparation and intended for use in this experiment.
Format: Multiple
Class: Link
Programmatic Pattern: _Link
Relation: Object[Sample]
Calibrant
A sample with known m/z (mass-to-charge ratios) used to calibrate the mass spectrometer.
Format: Single
Class: Link
Programmatic Pattern: _Link
SampleTemperature
The nominal temperature of the autosampler where the input samples are incubated prior to injection on the column.
Format: Single
Class: Real
Unit: 1 degree Celsius
Programmatic Pattern: GreaterEqualP[0 Kelvin]
SampleVolumes
For each member of SamplesIn, the volume taken from the sample and injected onto the column.
Format: Multiple
Class: Real
Unit: 1 microliter
Programmatic Pattern: GreaterEqualP[0 Micro Liter]
PlateSeal
The package of piercable, adhesive film used to cover plates of injection samples in this experiment in order to mitigate sample evaporation.
Format: Single
Class: Link
Programmatic Pattern: _Link
Aliquoting
AliquotSamplePreparation
For each member of AliquotSamples, parameters describing how aliquots should be drawn from the input samples after initial sample preparation in order to create new aliquot samples upon which aliquot preparation and the experiment should proceed.
Format: Multiple
[Aliquot]
Header: Aliquot
Class: Boolean
[AliquotAmount]
Header: AliquotAmount
Class: Expression
[TargetConcentration]
Header: TargetConcentration
Class: Expression
[AssayVolume]
Header: AssayVolume
Class: Real
Unit: 1 milliliter
[AliquotContainer]
Header: AliquotContainer
Class: Expression
[AssayBuffer]
Header: AssayBuffer
Class: Link
[BufferDiluent]
Header: BufferDiluent
Class: Link
[BufferDilutionFactor]
Header: BufferDilutionFactor
Class: Real
[ConcentratedBuffer]
Header: ConcentratedBuffer
Class: Link
[DestinationWell]
Header: DestinationWell
Class: Expression
[TargetConcentrationAnalyte]
Header: TargetConcentrationAnalyte
Class: Expression
[AliquotSampleLabel]
Header: AliquotSampleLabel
Class: String
AliquotProtocols
Protocols used to create AliquotSamples prior to starting the experiment.
Format: Multiple
Class: Link
Programmatic Pattern: _Link
Relation: Object[Protocol]
AliquotPreparationProtocols
Protocols used to mix, centrifuge, incubate, and filter the AliquotSamples prior to starting the experiment.
Format: Multiple
Class: Link
Programmatic Pattern: _Link
Relation: Object[Protocol]
AliquotSamples
Samples corresponding to aliquots of SamplesIn generated during sample preparation and intended for use in this experiment.
Format: Multiple
Class: Link
Programmatic Pattern: _Link
Relation: Object[Sample]
AliquotContainers
Containers that hold AliquotSamples generated during sample preparation and intended for use in this experiment.
Format: Multiple
Class: Link
Programmatic Pattern: _Link
SaveAliquots
Indicates if the AliquotSamples should be stored after the experiment, rather than being discarded.
Format: Single
Class: Expression
Programmatic Pattern: BooleanP
ConsolidateAliquots
Indicates if identical aliquots should be consolidated in a single sample.
Format: Single
Class: Expression
Programmatic Pattern: BooleanP
AliquotPreparation
Indicates if the aliquotting should occur manually or on a robotic liquid handler.
Format: Single
Class: Expression
Programmatic Pattern: PreparationMethodP
AliquotVolumes
For each member of SamplesIn, the volume transferred from the sample into the aliquot sample which is used in lieu of the initial sample for the experiment.
Format: Multiple
Class: Real
Unit: 1 microliter
Programmatic Pattern: GreaterP[0 Micro Liter]
AliquotMasses
For each member of SamplesIn, the mass of a solid transferred from the sample into the aliquot sample which is used in lieu of the initial sample for the experiment.
Format: Multiple
Class: Real
Unit: 1 milligram
Programmatic Pattern: GreaterP[0 Milligram]
AliquotAmounts
For each member of SamplesIn, the amount transferred from the sample into the aliquot sample which is used in lieu of the initial sample for the experiment.
Format: Multiple
Class: VariableUnit
Programmatic Pattern: GreaterP[0 Milliliter] | GreaterP[0 Milligram] | GreaterP[0 Unit, 1 Unit]
TargetConcentrations
For each member of SamplesIn, the final concentration of analyte in the aliquot sample which is used in lieu of the initial sample for the experiment.
Format: Multiple
Class: Expression
Programmatic Pattern: Milligram
Hold[GreaterP[0 Micro Molar] | GreaterP[0 ----------]]
Milliliter
AssayVolumes
For each member of SamplesIn (or PooledSamplesIn), the total volume of the reaction mixture which is used in lieu of the initial sample for the experiment.
Format: Multiple
Class: Real
Unit: 1 microliter
Programmatic Pattern: GreaterEqualP[0 Micro Liter]
AssayBuffers
For each member of SamplesIn (or PooledSamplesIn), the final buffers used to generate AliquotSamples by aliquoting SamplesIn.
Format: Multiple
Class: Link
Programmatic Pattern: _Link
ConcentratedBuffers
For each member of SamplesIn (or PooledSamplesIn), the concentrated buffer source which is added to the AliquotSamples to obtain 1x buffer concentration after dilution of the AliquotSamples which are used in lieu of the SamplesIn for the experiment.
Format: Multiple
Class: Link
Programmatic Pattern: _Link
BufferDilutionFactors
For each member of SamplesIn (or PooledSamplesIn), he dilution factor by which the concentrated buffer is diluted in preparing the AliquotSamples to obtain a 1x buffer concentration after dilution of the AliquotSamples which are used in lieu of the SamplesIn for the experiment.
Format: Multiple
Class: Real
Programmatic Pattern: GreaterP[0]
BufferDiluents
For each member of SamplesIn (or PooledSamplesIn), the diluent used to dilute the concentration of the concentrated buffer in preparing the AliquotSamples which are used in lieu of the SamplesIn for the experiment.
Format: Multiple
Class: Link
Programmatic Pattern: _Link
ConcentratedBuffer
The concentrated buffer source which is added to each of the AliquotSamples to obtain 1x buffer concentration after dilution of the AliquotSamples which are used in lieu of the SamplesIn for the experiment.
Format: Single
Class: Link
Programmatic Pattern: _Link
BufferDilutionFactor
The dilution factor by which the concentrated buffer is diluted in preparing the AliquotSamples to obtain a 1x buffer concentration after dilution of the AliquotSamples which are used in lieu of the SamplesIn for the experiment.
Format: Single
Class: Integer
Programmatic Pattern: GreaterP[0]
BufferDiluent
The diluent used to dilute the concentration of the concentrated buffer in preparing the AliquotSamples which are used in lieu of the SamplesIn for the experiment.
Format: Single
Class: Link
Programmatic Pattern: _Link
AssayBuffer
The desired buffer for the AliquotSamples which are used in lieu of the SamplesIn for the experiment.
Format: Single
Class: Link
Programmatic Pattern: _Link
Sample Post-Processing
PostProcessingProtocols
Protocols used to perform post-processing such as sample imaging or volume measurement.
Format: Multiple
Class: Link
Programmatic Pattern: _Link
Relation: Object[Protocol]
ImageSample
Indicates if the samples that are modified in the course of the experiment are imaged after running the experiment.
Format: Single
Class: Expression
Programmatic Pattern: BooleanP
MeasureVolume
Indicates if the volume of the liquid samples modified in the course of the experiment are measured after running the experiment.
Format: Single
Class: Expression
Programmatic Pattern: BooleanP
MeasureWeight
Indicates if the weight of the solid samples modified in the course of the experiment are measured after running the experiment.
Format: Single
Class: Expression
Programmatic Pattern: BooleanP
Measure
Indicates if the volume/weight of the samples modified in the course of the experiment are measured after running the experiment.
Format: Single
Class: Expression
Programmatic Pattern: BooleanP
Storage
Indicates the conditions under which any samples generated by this experiment are stored after the protocol is completed.
Format: Single
Class: Expression
Programmatic Pattern: SampleStorageTypeP | Disposal
Experimental Results
Data
Any primary data generated by this protocol.
Format: Multiple
Class: Link
Programmatic Pattern: _Link
Relation: Object[Data][Protocol]
SamplesOut
Any preparative samples generated by the protocol.
Format: Multiple
Class: Link
Programmatic Pattern: _Link
ContainersOut
Any containers holding SamplesOut generated by this protocol.
Format: Multiple
Class: Link
Programmatic Pattern: _Link
EnvironmentalData
Measurements of environmental conditions (temperature and humidity) recorded during the execution of this protocol.
Format: Multiple
Class: Link
Programmatic Pattern: _Link
Relation: Object[Data][Protocol]
StandardData
The chromatography traces generated for the standard's injection.
Format: Multiple
Class: Link
Programmatic Pattern: _Link
Relation: Object[Data][Protocol]
BlankData
The chromatography traces generated for the blank's injection.
Format: Multiple
Class: Link
Programmatic Pattern: _Link
Relation: Object[Data][Protocol]
PrimeData
Chromatography traces generated for any column prime runs.
Format: Multiple
Class: Link
Programmatic Pattern: _Link
Relation: Object[Data][Protocol]
FlushData
Chromatography traces generated for any column flush runs.
Format: Multiple
Class: Link
Programmatic Pattern: _Link
Relation: Object[Data][Protocol]
InitialAnalyteVolumes
The volume of each analyte sample (SamplesIn if drawn directly or AliquotSamples if instructed to aliquot prior to the assay) measured prior to injection.
Format: Multiple
Class: Real
Unit: 1 microliter
Programmatic Pattern: GreaterEqualP[0 Liter]
FinalAnalyteVolumes
The volume of each analyte sample (SamplesIn if drawn directly or AliquotSamples if instructed to aliquot prior to the assay) measured at the end of the protocol.
Format: Multiple
Class: Real
Unit: 1 microliter
Programmatic Pattern: GreaterEqualP[0 Liter]
InjectedAnalyteVolumes
The volume of each analyte sample (SamplesIn if drawn directly or AliquotSamples if instructed to aliquot prior to the assay) that was injected during the protocol, calculated as the difference between InitialAnalyteVolumes and FinalAnalyteVolumes.
Format: Multiple
Class: Real
Unit: 1 microliter
Programmatic Pattern: GreaterEqualP[0 Liter]
Troubleshooting
TroubleshootingReports
Reports for errors that require troubleshooting associated with the execution of this top-level protocol.
Format: Multiple
Class: Link
Programmatic Pattern: _Link
Resources
AwaitingResources
Indicates if this protocol is awaiting the arrival of items before it can be begun or continued.
Format: Single
Class: Boolean
Programmatic Pattern: BooleanP
ShippingMaterials
Indicates the transactions, and the specific products or samples therein, that must be received before this protocol can be begun or continued.
Format: Multiple
[[1]] Transaction
Header: Transaction
Class: Link
Programmatic Pattern: _Link
[[2]] Required Product
Header: Required Product
Class: Link
Programmatic Pattern: _Link
HazardousWaste
The types of waste generated by this protocol.
Format: Multiple
Class: Link
Programmatic Pattern: _Link
DispenserContainers
Containers gathered as destinations for any resources obtained from a chemical dispenser.
Format: Multiple
Class: Link
Programmatic Pattern: _Link
GasSources
A list of containers that supplied gas to instruments in this protocol through plumbing connections.
Format: Multiple
[[1]] Gas Type
Header: Gas Type
Class: Expression
Programmatic Pattern: GasP
[[2]] Source Container
Header: Source Container
Class: Link
Programmatic Pattern: _Link
Relation: Object[Container]
[[3]] Supplied Instrument
Header: Supplied Instrument
Class: Link
Programmatic Pattern: _Link
Relation: Object[Instrument]
Cleaning
WasteGenerated
For each type of waste generated by this protocol, the total amount (in grams) generated during the conduct of the protocol.
Format: Multiple
[Waste]
Header: Waste
Class: Link
Relation: Model[Sample]
[Weight]
Header: Weight
Class: Real
Unit: 1 gram
ExternalNeedleWashSolution
The solution used to wash the outside of the injection needle and pumps before, during, and after the experiment.
Format: Single
Class: Link
Programmatic Pattern: _Link
NeedleWashSolution
The solution used to wash the inside of the injection needle and pumps before, during, and after the experiment.
Format: Single
Class: Link
Programmatic Pattern: _Link
Storage Information
StoragePrice
The total monthly price for warehousing all user owned items associated with this protocol in an ECL facility under the storage conditions specified by each item.
Format: Single
Class: Real
Unit: 1 US dollar per month
Programmatic Pattern: USD
Hold[GreaterEqualP[0 -----]]
Month
Sample Storage
SamplesInStorage
For each member of SamplesIn, The storage conditions under which any input samples to this experiment should be stored after their usage in this experiment.
Format: Multiple
Class: Expression
Programmatic Pattern: SampleStorageTypeP | Disposal
AliquotStorage
For each member of AliquotSamples, The storage conditions under which any aliquot samples generated by this experiment should be stored after the protocol is completed.
Format: Multiple
Class: Expression
Programmatic Pattern: SampleStorageTypeP | Disposal
SamplesOutStorage
For each member of SamplesOut, the storage conditions under which any output samples generated by this experiment should be stored after the protocol is completed.
Format: Multiple
Class: Expression
Programmatic Pattern: SampleStorageTypeP | Disposal
Option Handling
ResolvedOptions
The final options used as parameters for this protocol, after automatic options are resolved.
Format: Single
Class: Compressed
Programmatic Pattern: {_Rule...}
UnresolvedOptions
The verbatim options originally input by the protocol author to generate this protocol, often with some options set to Automatic.
Format: Single
Class: Compressed
Programmatic Pattern: {_Rule...}
Computations
ParallelComputations
List of computational jobs generated and run in parallel to the execution of this protocol.
Format: Multiple
Class: Link
Programmatic Pattern: _Link
ComputationsOutstanding
Indicates if any of the computation jobs in ParallelComputations have not yet completed.
Format: Single
Class: Boolean
Programmatic Pattern: BooleanP
ErroneousComputations
List of computational jobs generated and run in parallel to the execution of this protocol in which a warning or error was thown, or that did not finish.
Format: Multiple
Class: Link
Programmatic Pattern: _Link
Column Installation
ColumnSelection
The stationary phase device(s) through which the Cosolvents and input samples flow. It adsorbs and separates the molecules within the sample based on the properties of the Cosolvents, samples, column material, and ColumnTemperature.
Format: Multiple
Class: Link
Programmatic Pattern: _Link
ColumnOrientation
For each member of ColumnSelection, the direction of the Column for the protocol with respect to the flow.
Format: Multiple
Class: Expression
Programmatic Pattern: ColumnOrientationP
Column Prime
ColumnPrimeGradientMethods
For each member of ColumnSelection, the composition of the CO2 and cosolvents within the flow, defined for specific time points during the equilibration of the columns (column prime).
Format: Multiple
Class: Link
Programmatic Pattern: _Link
Relation: Object[Method]
ColumnPrimeCO2Gradient
For each member of ColumnSelection, the percentage of supercritical CO2 in the composition over time, in the form: {Time, % CO2} or a single % CO2 for each column prime run.
Format: Multiple
Class: Expression
Programmatic Pattern: {{GreaterEqualP[0 Minute], RangeP[0 Percent, 100 Percent]}...} | RangeP[0 Percent, 100 Percent]
ColumnPrimeGradientA
For each member of ColumnSelection, the percentage of CosolventA in the composition over time, in the form: {Time, % Cosolvent A} or a single % Cosolvent A for each column prime run.
Format: Multiple
Class: Expression
Programmatic Pattern: {{GreaterEqualP[0 Minute], RangeP[0 Percent, 100 Percent]}...} | RangeP[0 Percent, 100 Percent]
ColumnPrimeGradientB
For each member of ColumnSelection, the percentage of CosolventB in the composition over time, in the form: {Time, % Cosolvent B} or a single % Cosolvent B for each column prime run.
Format: Multiple
Class: Expression
Programmatic Pattern: {{GreaterEqualP[0 Minute], RangeP[0 Percent, 100 Percent]}...} | RangeP[0 Percent, 100 Percent]
ColumnPrimeGradientC
For each member of ColumnSelection, the percentage of CosolventC in the composition over time, in the form: {Time, % Cosolvent C} or a single % Cosolvent C for each column prime run.
Format: Multiple
Class: Expression
Programmatic Pattern: {{GreaterEqualP[0 Minute], RangeP[0 Percent, 100 Percent]}...} | RangeP[0 Percent, 100 Percent]
ColumnPrimeGradientD
For each member of ColumnSelection, the percentage of CosolventD in the composition over time, in the form: {Time, % Cosolvent D} or a single % Cosolvent D for each column prime run.
Format: Multiple
Class: Expression
Programmatic Pattern: {{GreaterEqualP[0 Minute], RangeP[0 Percent, 100 Percent]}...} | RangeP[0 Percent, 100 Percent]
ColumnPrimeBackPressure
For each member of ColumnSelection, the applied pressure between the atmosphere and the PhotoDiodeArray detector exit, in the form: {Time, BackPressure} or a single BackPressure for each column prime run.
Format: Multiple
Class: Expression
Programmatic Pattern: {{GreaterEqualP[0 Minute], GreaterP[0 PSI]}...} | GreaterP[0 PSI]
ColumnPrimeFlowRates
For each member of ColumnSelection, the total rate of mobile phase pumped through the instrument for each column prime.
Format: Multiple
Class: Expression
Programmatic Pattern: Milliliter 0 Milli Liter
Hold[ListableP[{GreaterEqualP[0 Minute], GreaterEqualP[0 ----------]}] | GreaterEqualP[-------------]]
Minute Minute
ColumnPrimeTemperatures
For each member of ColumnSelection, the nominal temperature of the column compartment for each column prime run.
Format: Multiple
Class: Real
Unit: 1 degree Celsius
Programmatic Pattern: GreaterEqualP[0 Kelvin]
ColumnPrimeIonModes
For each member of ColumnSelection, indicates if positively or negatively charged ions are analyzed each column prime run.
Format: Multiple
Class: Expression
Programmatic Pattern: IonModeP
ColumnPrimeMakeupFlowRates
For each member of ColumnSelection, the total rate of MakeupSolvent pumped through the instrument for each column prime.
Format: Multiple
Class: Expression
Programmatic Pattern: Milliliter 0 Milli Liter
Hold[ListableP[{GreaterEqualP[0 Minute], GreaterEqualP[0 ----------]}] | GreaterEqualP[-------------]]
Minute Minute
ColumnPrimeMassSelections
For each member of ColumnSelection, the all of the mass-to-charge ratio (m/z) measured via mass spectrometry.
Format: Multiple
Class: Expression
Programmatic Pattern: 0 Gram
Hold[{GreaterP[------]..}]
Mole
ColumnPrimeMinMasses
For each member of ColumnSelection, the lowest measured mass-to-charge ratio (m/z) value.
Format: Multiple
Class: Real
Unit: 1 gram per mole
Programmatic Pattern: 0 Gram
Hold[GreaterEqualP[------]]
Mole
ColumnPrimeMaxMasses
For each member of ColumnSelection, the highest measured mass-to-charge ratio (m/z) value.
Format: Multiple
Class: Real
Unit: 1 gram per mole
Programmatic Pattern: 0 Gram
Hold[GreaterP[------]]
Mole
ColumnPrimeProbeTemperatures
For each member of ColumnSelection, the temperature of the needle that sprays column effluent into the ionization chamber for each ColumnPrime run.
Format: Multiple
Class: Real
Unit: 1 degree Celsius
Programmatic Pattern: GreaterP[0 Celsius]
ColumnPrimeSourceTemperatures
For each member of ColumnSelection, the temperature that the source block is set to in order to discourage condensation and decrease solvent clustering in the reduced vacuum region of the source.
The source block is the metallic chamber with reduced pressure separating the sprayer (at atmospheric pressure) and the inside of the mass spectrometer (at 10^-7 Torr of pressure). It consists of the sampling cone, the isolation valve, and the ion block. The source temperature setting affects sensitivity.
Format: Multiple
Class: Real
Unit: 1 degree Celsius
Programmatic Pattern: GreaterP[0 Celsius]
ColumnPrimeESICapillary Voltages
For each member of ColumnSelection, the applied voltage differential between the injector and the inlet plate for the mass spectrometry in order to ionize analyte molecules.
Format: Multiple
Class: Real
Unit: 1 volt
Programmatic Pattern: GreaterP[0 Volt]
ColumnPrimeSamplingCone Voltages
For each member of ColumnSelection, the voltage offset between the 1st and 2nd stage of the stepwave ion guide which leads ions coming from the sample cone (the metal shield covering the front of the source block), towards the quadrupole mass analyzer.
Format: Multiple
Class: Real
Unit: 1 volt
Programmatic Pattern: GreaterP[0 Volt]
ColumnPrimeScanTimes
For each member of ColumnSelection, the duration of time allowed to pass between each spectral acquisition.
Format: Multiple
Class: Real
Unit: 1 second
Programmatic Pattern: GreaterP[0 Second]
ColumnPrimeMassDetectionGains
For each member of ColumnSelection, indicates the arbitrary-scaled signal amplification of the mass spectrometry measurement.
Format: Multiple
Class: Real
Programmatic Pattern: RangeP[0.01, 1000., 0.01]
ColumnPrimeAbsorbance Selection
For each member of ColumnSelection, all the wavelengths of light absorbed in the detector's flow cell for a PhotoDiodeArray (PDA) detector for each column prime.
Format: Multiple
Class: Expression
Programmatic Pattern: {GreaterP[0 Centimeter]..}
ColumnPrimeMinAbsorbance Wavelengths
For each member of ColumnSelection, the wavelength of light absorbed in the detector's flow cell for a PDA detector.
Format: Multiple
Class: Real
Unit: 1 nanometer
Programmatic Pattern: GreaterP[0 Centimeter]
ColumnPrimeMaxAbsorbance Wavelengths
For each member of ColumnSelection, the maximum wavelength of light absorbed in the detector's flow cell for a PDA detector.
Format: Multiple
Class: Real
Unit: 1 nanometer
Programmatic Pattern: GreaterP[0 Centimeter]
ColumnPrimeWavelength Resolutions
For each member of ColumnSelection, the increment in wavelength of light absorbed in the detector's flow cell for a PDA detector.
Format: Multiple
Class: Real
Unit: 1 nanometer
Programmatic Pattern: GreaterP[0 Centimeter]
ColumnPrimeUVFilter
For each member of ColumnSelection, indicates whether or not to block UV wavelengths (less than 210 nm) from being transmitted through the sample for PDA detector.
Format: Multiple
Class: Boolean
Programmatic Pattern: BooleanP
ColumnPrimeAbsorbanceSampling Rates
For each member of ColumnSelection, indicates the frequency of measurement for UVVis or PDA detectors.
Format: Multiple
Class: Real
Unit: 1 reciprocal second
Programmatic Pattern: 1
Hold[GreaterP[0 ------]]
Second
Gradient
GradientMethods
For each member of SamplesIn, the CO2 and solvent gradient used for purification.
Format: Multiple
Class: Link
Programmatic Pattern: _Link
Relation: Object[Method]
CO2Gradient
For each member of SamplesIn, the percentage of supercritical CO2 in the composition over time, in the form: {Time, % CO2} or a single % CO2 for the entire run.
Format: Multiple
Class: Expression
Programmatic Pattern: {{GreaterEqualP[0 Minute], RangeP[0 Percent, 100 Percent]}...} | RangeP[0 Percent, 100 Percent]
GradientA
For each member of SamplesIn, the percentage of CosolventA in the composition over time, in the form: {Time, % Cosolvent A} or a single % Cosolvent A for the entire run.
Format: Multiple
Class: Expression
Programmatic Pattern: {{GreaterEqualP[0 Minute], RangeP[0 Percent, 100 Percent]}...} | RangeP[0 Percent, 100 Percent]
GradientB
For each member of SamplesIn, the percentage of CosolventB in the composition over time, in the form: {Time, % Cosolvent B} or a single % Cosolvent B for the entire run.
Format: Multiple
Class: Expression
Programmatic Pattern: {{GreaterEqualP[0 Minute], RangeP[0 Percent, 100 Percent]}...} | RangeP[0 Percent, 100 Percent]
GradientC
For each member of SamplesIn, the percentage of CosolventC in the composition over time, in the form: {Time, % Cosolvent C} or a single % Cosolvent C for the entire run.
Format: Multiple
Class: Expression
Programmatic Pattern: {{GreaterEqualP[0 Minute], RangeP[0 Percent, 100 Percent]}...} | RangeP[0 Percent, 100 Percent]
GradientD
For each member of SamplesIn, the percentage of CosolventD in the composition over time, in the form: {Time, % Cosolvent D} or a single % Cosolvent D for the entire run.
Format: Multiple
Class: Expression
Programmatic Pattern: {{GreaterEqualP[0 Minute], RangeP[0 Percent, 100 Percent]}...} | RangeP[0 Percent, 100 Percent]
BackPressures
For each member of SamplesIn, the applied pressure between the atmosphere and the PhotoDiodeArray detector exit, in the form: {Time, BackPressure} or a single BackPressure for the entire run.
Format: Multiple
Class: Expression
Programmatic Pattern: {{GreaterEqualP[0 Minute], GreaterP[0 PSI]}...} | GreaterP[0 PSI]
FlowRate
For each member of SamplesIn, the total rate of mobile phase pumped through the instrument.
Format: Multiple
Class: Expression
Programmatic Pattern: Milliliter 0 Milli Liter
Hold[ListableP[{GreaterEqualP[0 Minute], GreaterEqualP[0 ----------]}] | GreaterEqualP[-------------]]
Minute Minute
Columns
For each member of SamplesIn, the column used from the column selector for the separation and measurement.
Format: Multiple
Class: Link
Programmatic Pattern: _Link
ColumnTemperatures
For each member of SamplesIn, the nominal temperature of the column compartment during a run.
Format: Multiple
Class: Real
Unit: 1 degree Celsius
Programmatic Pattern: GreaterEqualP[0 Kelvin]
FinalCosolventAVolume
The volume of CosolventA immediately after the experiment was completed.
Format: Single
Class: Real
Unit: 1 liter
Programmatic Pattern: GreaterEqualP[0 Liter]
FinalCosolventBVolume
The volume of CosolventB immediately after the experiment was completed.
Format: Single
Class: Real
Unit: 1 liter
Programmatic Pattern: GreaterEqualP[0 Liter]
FinalCosolventCVolume
The volume of CosolventC immediately after the experiment was completed.
Format: Single
Class: Real
Unit: 1 liter
Programmatic Pattern: GreaterEqualP[0 Liter]
FinalCosolventDVolume
The volume of CosolventD immediately after the experiment was completed.
Format: Single
Class: Real
Unit: 1 liter
Programmatic Pattern: GreaterEqualP[0 Liter]
FinalMakeupSolventVolume
The volume of MakeupSolvent immediately after the experiment was started.
Format: Single
Class: Real
Unit: 1 liter
Programmatic Pattern: GreaterEqualP[0 Liter]
FinalCosolventAAppearance
An image of CosolventA taken immediately after the experiment was completed.
Format: Single
Class: Link
Programmatic Pattern: _Link
Relation: Object[EmeraldCloudFile]
FinalCosolventBAppearance
An image of CosolventB taken immediately after the experiment was completed.
Format: Single
Class: Link
Programmatic Pattern: _Link
Relation: Object[EmeraldCloudFile]
FinalCosolventCAppearance
An image of CosolventC taken immediately after the experiment was completed.
Format: Single
Class: Link
Programmatic Pattern: _Link
Relation: Object[EmeraldCloudFile]
FinalCosolventDAppearance
An image of CosolventD taken immediately after the experiment was completed.
Format: Single
Class: Link
Programmatic Pattern: _Link
Relation: Object[EmeraldCloudFile]
FinalMakeupSolventAppearance
An image of MakeupSolvent taken immediately after the experiment was completed.
Format: Single
Class: Link
Programmatic Pattern: _Link
Relation: Object[EmeraldCloudFile]
Detection
IonModes
For each member of SamplesIn, indicates if positively or negatively charged ions are analyzed each column prime run.
Format: Multiple
Class: Expression
Programmatic Pattern: IonModeP
MakeupFlowRates
For each member of SamplesIn, the total rate of MakeupSolvent pumped through the instrument for each column prime.
Format: Multiple
Class: Expression
Programmatic Pattern: Milliliter 0 Milli Liter
Hold[ListableP[{GreaterEqualP[0 Minute], GreaterEqualP[0 ----------]}] | GreaterEqualP[-------------]]
Minute Minute
MassSelection
For each member of SamplesIn, all of the mass-to-charge ratio (m/z) measured via mass spectrometry.
Format: Multiple
Class: Expression
Programmatic Pattern: 0 Gram
Hold[{GreaterP[------]..}]
Mole
MinMasses
For each member of SamplesIn, the lowest measured mass-to-charge ratio (m/z) value.
Format: Multiple
Class: Real
Unit: 1 gram per mole
Programmatic Pattern: 0 Gram
Hold[GreaterEqualP[------]]
Mole
MaxMasses
For each member of SamplesIn, the highest measured mass-to-charge ratio (m/z) value.
Format: Multiple
Class: Real
Unit: 1 gram per mole
Programmatic Pattern: 0 Gram
Hold[GreaterP[------]]
Mole
ProbeTemperatures
For each member of SamplesIn, the temperature of the needle that sprays column effluent into the ionization chamber.
Format: Multiple
Class: Real
Unit: 1 degree Celsius
Programmatic Pattern: GreaterP[0 Celsius]
SourceTemperatures
For each member of SamplesIn, the temperature that the source block is set to in order to discourage condensation and decrease solvent clustering in the reduced vacuum region of the source.
The source block is the metallic chamber with reduced pressure separating the sprayer (at atmospheric pressure) and the inside of the mass spectrometer (at 10^-7 Torr of pressure). It consists of the sampling cone, the isolation valve, and the ion block. The source temperature setting affects sensitivity.
Format: Multiple
Class: Real
Unit: 1 degree Celsius
Programmatic Pattern: GreaterP[0 Celsius]
ESICapillaryVoltages
For each member of SamplesIn, the applied voltage differential between the injector and the inlet plate for the mass spectrometry in order to ionize analyte molecules.
Format: Multiple
Class: Real
Unit: 1 volt
Programmatic Pattern: GreaterP[0 Volt]
SamplingConeVoltages
For each member of SamplesIn, the voltage offset between the 1st and 2nd stage of the stepwave ion guide which leads ions coming from the sample cone (the metal shield covering the front of the source block), towards the quadrupole mass analyzer.
Format: Multiple
Class: Real
Unit: 1 volt
Programmatic Pattern: GreaterP[0 Volt]
ScanTimes
For each member of SamplesIn, the duration of time allowed to pass between each spectral acquisition.
Format: Multiple
Class: Real
Unit: 1 second
Programmatic Pattern: GreaterP[0 Second]
MassDetectionGains
For each member of SamplesIn, indicates the arbitrary-scaled signal amplification of the mass spectrometry measurement.
Format: Multiple
Class: Real
Programmatic Pattern: RangeP[0.01, 1000., 0.01]
AbsorbanceSelection
For each member of SamplesIn, all the wavelengths of light absorbed in the detector's flow cell for a PhotoDiodeArray (PDA) detector.
Format: Multiple
Class: Expression
Programmatic Pattern: {GreaterP[0 Centimeter]..}
MinAbsorbanceWavelengths
For each member of SamplesIn, the minimum wavelength of light absorbed in the detector's flow cell for a PDA detector.
Format: Multiple
Class: Real
Unit: 1 nanometer
Programmatic Pattern: GreaterP[0 Centimeter]
MaxAbsorbanceWavelengths
For each member of SamplesIn, the maximum wavelength of light absorbed in the detector's flow cell for a PDA detector.
Format: Multiple
Class: Real
Unit: 1 nanometer
Programmatic Pattern: GreaterP[0 Centimeter]
WavelengthResolutions
For each member of SamplesIn, the increment in wavelength of light absorbed in the detector's flow cell for a PDA detector.
Format: Multiple
Class: Real
Unit: 1 nanometer
Programmatic Pattern: GreaterP[0 Centimeter]
UVFilters
For each member of SamplesIn, indicates whether or not to block UV wavelengths (less than 210 nm) from being transmitted through the sample for Absorbance detectors (PDA).
Format: Multiple
Class: Boolean
Programmatic Pattern: BooleanP
AbsorbanceSamplingRates
For each member of SamplesIn, indicates the frequency of measurement for PDA detectors.
Format: Multiple
Class: Real
Unit: 1 reciprocal second
Programmatic Pattern: 1
Hold[GreaterP[0 ------]]
Second
Standards
Standards
Samples with known profiles used to calibrate peak integrations and retention times for a given run.
Format: Multiple
Class: Link
Programmatic Pattern: _Link
StandardSampleVolumes
For each member of Standards, the volume taken from the standard and injected onto the column.
Format: Multiple
Class: Real
Unit: 1 microliter
Programmatic Pattern: GreaterEqualP[0 Micro Liter]
StandardGradientMethods
For each member of Standards, the method used to describe the gradient used for purification.
Format: Multiple
Class: Link
Programmatic Pattern: _Link
Relation: Object[Method]
StandardCO2Gradient
For each member of Standards, the percentage of supercritical CO2 in the composition over time, in the form: {Time, % CO2} or a single % CO2 for the entire run.
Format: Multiple
Class: Expression
Programmatic Pattern: {{GreaterEqualP[0 Minute], RangeP[0 Percent, 100 Percent]}...} | RangeP[0 Percent, 100 Percent]
StandardGradientA
For each member of Standards, the percentage of CosolventA in the composition over time, in the form: {Time, % Cosolvent A} or a single % Cosolvent A for the entire run.
Format: Multiple
Class: Expression
Programmatic Pattern: {{GreaterEqualP[0 Minute], RangeP[0 Percent, 100 Percent]}...} | RangeP[0 Percent, 100 Percent]
StandardGradientB
For each member of Standards, the percentage of CosolventB in the composition over time, in the form: {Time, % Cosolvent B} or a single % Cosolvent B for the entire run.
Format: Multiple
Class: Expression
Programmatic Pattern: {{GreaterEqualP[0 Minute], RangeP[0 Percent, 100 Percent]}...} | RangeP[0 Percent, 100 Percent]
StandardGradientC
For each member of Standards, the percentage of CosolventC in the composition over time, in the form: {Time, % Cosolvent C} or a single % Cosolvent C for the entire run.
Format: Multiple
Class: Expression
Programmatic Pattern: {{GreaterEqualP[0 Minute], RangeP[0 Percent, 100 Percent]}...} | RangeP[0 Percent, 100 Percent]
StandardGradientD
For each member of Standards, the percentage of CosolventD in the composition over time, in the form: {Time, % Cosolvent D} or a single % Cosolvent D for the entire run.
Format: Multiple
Class: Expression
Programmatic Pattern: {{GreaterEqualP[0 Minute], RangeP[0 Percent, 100 Percent]}...} | RangeP[0 Percent, 100 Percent]
StandardBackPressures
For each member of Standards, the applied pressure between the atmosphere and the PhotoDiodeArray detector exit, in the form: {Time, BackPressure} or a single BackPressure for the entire run.
Format: Multiple
Class: Expression
Programmatic Pattern: {{GreaterEqualP[0 Minute], GreaterP[0 PSI]}...} | GreaterP[0 PSI]
StandardFlowRates
For each member of Standards, the total rate of mobile phase pumped through the instrument.
Format: Multiple
Class: Expression
Programmatic Pattern: Milliliter 0 Milli Liter
Hold[ListableP[{GreaterEqualP[0 Minute], GreaterEqualP[0 ----------]}] | GreaterEqualP[-------------]]
Minute Minute
StandardColumns
For each member of Standards, the column used from the column selector for the separation and measurement.
Format: Multiple
Class: Link
Programmatic Pattern: _Link
StandardColumnTemperatures
For each member of Standards, the nominal temperature of the column compartment during a run.
Format: Multiple
Class: Real
Unit: 1 degree Celsius
Programmatic Pattern: GreaterEqualP[0 Kelvin]
StandardIonModes
For each member of Standards, indicates if positively or negatively charged ions are analyzed each column prime run.
Format: Multiple
Class: Expression
Programmatic Pattern: IonModeP
StandardMakeupFlowRates
For each member of Standards, the total rate of MakeupSolvent pumped through the instrument for each column prime.
Format: Multiple
Class: Expression
Programmatic Pattern: Milliliter 0 Milli Liter
Hold[ListableP[{GreaterEqualP[0 Minute], GreaterEqualP[0 ----------]}] | GreaterEqualP[-------------]]
Minute Minute
StandardMassSelection
For each member of Standards, all of the mass-to-charge ratio (m/z) measured via mass spectrometry.
Format: Multiple
Class: Expression
Programmatic Pattern: 0 Gram
Hold[{GreaterP[------]..}]
Mole
StandardMinMasses
For each member of Standards, the lowest measured mass-to-charge ratio (m/z) value.
Format: Multiple
Class: Real
Unit: 1 gram per mole
Programmatic Pattern: 0 Gram
Hold[GreaterEqualP[------]]
Mole
StandardMaxMasses
For each member of Standards, the highest measured mass-to-charge ratio (m/z) value.
Format: Multiple
Class: Real
Unit: 1 gram per mole
Programmatic Pattern: 0 Gram
Hold[GreaterP[------]]
Mole
StandardProbeTemperatures
For each member of Standards, the temperature of the needle that sprays column effluent into the ionization chamber.
Format: Multiple
Class: Real
Unit: 1 degree Celsius
Programmatic Pattern: GreaterP[0 Celsius]
StandardSourceTemperatures
For each member of Standards, the temperature that the source block is set to in order to discourage condensation and decrease solvent clustering in the reduced vacuum region of the source.
The source block is the metallic chamber with reduced pressure separating the sprayer (at atmospheric pressure) and the inside of the mass spectrometer (at 10^-7 Torr of pressure). It consists of the sampling cone, the isolation valve, and the ion block. The source temperature setting affects sensitivity.
Format: Multiple
Class: Real
Unit: 1 degree Celsius
Programmatic Pattern: GreaterP[0 Celsius]
StandardESICapillaryVoltages
For each member of Standards, the applied voltage differential between the injector and the inlet plate for the mass spectrometry in order to ionize analyte molecules.
Format: Multiple
Class: Real
Unit: 1 volt
Programmatic Pattern: GreaterP[0 Volt]
StandardSamplingConeVoltages
For each member of Standards, the voltage offset between the 1st and 2nd stage of the stepwave ion guide which leads ions coming from the sample cone (the metal shield covering the front of the source block), towards the quadrupole mass analyzer.
Format: Multiple
Class: Real
Unit: 1 volt
Programmatic Pattern: GreaterP[0 Volt]
StandardScanTimes
For each member of Standards, the duration of time allowed to pass between each spectral acquisition.
Format: Multiple
Class: Real
Unit: 1 second
Programmatic Pattern: GreaterP[0 Second]
StandardMassDetectionGains
For each member of Standards, indicates the arbitrary-scaled signal amplification of the mass spectrometry measurement.
Format: Multiple
Class: Real
Programmatic Pattern: RangeP[0.01, 1000., 0.01]
StandardAbsorbanceSelection
For each member of Standards, all the wavelengths of light absorbed in the detector's flow cell for a PhotoDiodeArray (PDA) detector.
Format: Multiple
Class: Expression
Programmatic Pattern: {GreaterP[0 Centimeter]..}
StandardMinAbsorbance Wavelengths
For each member of Standards, the wavelength of light absorbed in the detector's flow cell for a PDA detector.
Format: Multiple
Class: Real
Unit: 1 nanometer
Programmatic Pattern: GreaterP[0 Centimeter]
StandardMaxAbsorbance Wavelengths
For each member of Standards, the maximum wavelength of light absorbed in the detector's flow cell for a PDA detector.
Format: Multiple
Class: Real
Unit: 1 nanometer
Programmatic Pattern: GreaterP[0 Centimeter]
StandardWavelengthResolutions
For each member of Standards, the increment in wavelength of light absorbed in the detector's flow cell for a PDA detector.
Format: Multiple
Class: Real
Unit: 1 nanometer
Programmatic Pattern: GreaterP[0 Centimeter]
StandardUVFilters
For each member of Standards, indicates whether or not to block UV wavelengths (less than 210 nm) from being transmitted through the sample for Absorbance detectors (PDA).
Format: Multiple
Class: Boolean
Programmatic Pattern: BooleanP
StandardAbsorbanceSampling Rates
For each member of Standards, indicates the frequency of measurement for PDA detectors.
Format: Multiple
Class: Real
Unit: 1 reciprocal second
Programmatic Pattern: 1
Hold[GreaterP[0 ------]]
Second
StandardsStorageConditions
For each member of Standards, the storage conditions under which the standard samples should be stored after the protocol is completed.
Format: Multiple
Class: Expression
Programmatic Pattern: SampleStorageTypeP | Disposal
Blanking
Blanks
Buffer only samples injected to asses background signal from the buffers and column in the absence of injected analyte.
Format: Multiple
Class: Link
Programmatic Pattern: _Link
BlankSampleVolumes
For each member of Blanks, the volume taken from the blank and injected onto the column.
Format: Multiple
Class: Real
Unit: 1 microliter
Programmatic Pattern: GreaterEqualP[0 Micro Liter]
BlankGradientMethods
For each member of Blanks, the method used to describe the gradient used for purification.
Format: Multiple
Class: Link
Programmatic Pattern: _Link
Relation: Object[Method]
BlankCO2Gradient
For each member of Blanks, the percentage of supercritical CO2 in the composition over time, in the form: {Time, % CO2} or a single % CO2 for the entire run.
Format: Multiple
Class: Expression
Programmatic Pattern: {{GreaterEqualP[0 Minute], RangeP[0 Percent, 100 Percent]}...} | RangeP[0 Percent, 100 Percent]
BlankGradientA
For each member of Blanks, the percentage of CosolventA in the composition over time, in the form: {Time, % Cosolvent A} or a single % Cosolvent A for the entire run.
Format: Multiple
Class: Expression
Programmatic Pattern: {{GreaterEqualP[0 Minute], RangeP[0 Percent, 100 Percent]}...} | RangeP[0 Percent, 100 Percent]
BlankGradientB
For each member of Blanks, the percentage of CosolventB in the composition over time, in the form: {Time, % Cosolvent B} or a single % Cosolvent B for the entire run.
Format: Multiple
Class: Expression
Programmatic Pattern: {{GreaterEqualP[0 Minute], RangeP[0 Percent, 100 Percent]}...} | RangeP[0 Percent, 100 Percent]
BlankGradientC
For each member of Blanks, the percentage of CosolventC in the composition over time, in the form: {Time, % Cosolvent C} or a single % Cosolvent C for the entire run.
Format: Multiple
Class: Expression
Programmatic Pattern: {{GreaterEqualP[0 Minute], RangeP[0 Percent, 100 Percent]}...} | RangeP[0 Percent, 100 Percent]
BlankGradientD
For each member of Blanks, the percentage of CosolventD in the composition over time, in the form: {Time, % Cosolvent D} or a single % Cosolvent D for the entire run.
Format: Multiple
Class: Expression
Programmatic Pattern: {{GreaterEqualP[0 Minute], RangeP[0 Percent, 100 Percent]}...} | RangeP[0 Percent, 100 Percent]
BlankBackPressures
For each member of Blanks, the applied pressure between the atmosphere and the PhotoDiodeArray detector exit, in the form: {Time, BackPressure} or a single BackPressure for the entire run.
Format: Multiple
Class: Expression
Programmatic Pattern: {{GreaterEqualP[0 Minute], GreaterP[0 PSI]}...} | GreaterP[0 PSI]
BlankFlowRates
For each member of Blanks, the total rate of mobile phase pumped through the instrument.
Format: Multiple
Class: Expression
Programmatic Pattern: Milliliter 0 Milli Liter
Hold[ListableP[{GreaterEqualP[0 Minute], GreaterEqualP[0 ----------]}] | GreaterEqualP[-------------]]
Minute Minute
BlankColumns
For each member of Blanks, the column used from the column selector for the separation and measurement.
Format: Multiple
Class: Link
Programmatic Pattern: _Link
BlankColumnTemperatures
For each member of Blanks, the nominal temperature of the column compartment during a run.
Format: Multiple
Class: Real
Unit: 1 degree Celsius
Programmatic Pattern: GreaterEqualP[0 Kelvin]
BlankIonModes
For each member of Blanks, indicates if positively or negatively charged ions are analyzed each column prime run.
Format: Multiple
Class: Expression
Programmatic Pattern: IonModeP
BlankMakeupFlowRates
For each member of Blanks, the total rate of MakeupSolvent pumped through the instrument for each column prime.
Format: Multiple
Class: Expression
Programmatic Pattern: Milliliter 0 Milli Liter
Hold[ListableP[{GreaterEqualP[0 Minute], GreaterEqualP[0 ----------]}] | GreaterEqualP[-------------]]
Minute Minute
BlankMassSelection
For each member of Blanks, all of the mass-to-charge ratio (m/z) measured via mass spectrometry.
Format: Multiple
Class: Expression
Programmatic Pattern: 0 Gram
Hold[{GreaterP[------]..}]
Mole
BlankMinMasses
For each member of Blanks, the lowest measured mass-to-charge ratio (m/z) value.
Format: Multiple
Class: Real
Unit: 1 gram per mole
Programmatic Pattern: 0 Gram
Hold[GreaterEqualP[------]]
Mole
BlankMaxMasses
For each member of Blanks, the highest measured mass-to-charge ratio (m/z) value.
Format: Multiple
Class: Real
Unit: 1 gram per mole
Programmatic Pattern: 0 Gram
Hold[GreaterP[------]]
Mole
BlankProbeTemperatures
For each member of Blanks, the temperature of the needle that sprays column effluent into the ionization chamber.
Format: Multiple
Class: Real
Unit: 1 degree Celsius
Programmatic Pattern: GreaterP[0 Celsius]
BlankSourceTemperatures
For each member of Blanks, the temperature that the source block is set to in order to discourage condensation and decrease solvent clustering in the reduced vacuum region of the source.
The source block is the metallic chamber with reduced pressure separating the sprayer (at atmospheric pressure) and the inside of the mass spectrometer (at 10^-7 Torr of pressure). It consists of the sampling cone, the isolation valve, and the ion block. The source temperature setting affects sensitivity.
Format: Multiple
Class: Real
Unit: 1 degree Celsius
Programmatic Pattern: GreaterP[0 Celsius]
BlankESICapillaryVoltages
For each member of Blanks, the applied voltage differential between the injector and the inlet plate for the mass spectrometry in order to ionize analyte molecules.
Format: Multiple
Class: Real
Unit: 1 volt
Programmatic Pattern: GreaterP[0 Volt]
BlankSamplingConeVoltages
For each member of Blanks, the voltage offset between the 1st and 2nd stage of the stepwave ion guide which leads ions coming from the sample cone (the metal shield covering the front of the source block), towards the quadrupole mass analyzer.
Format: Multiple
Class: Real
Unit: 1 volt
Programmatic Pattern: GreaterP[0 Volt]
BlankScanTimes
For each member of Blanks, the duration of time allowed to pass between each spectral acquisition.
Format: Multiple
Class: Real
Unit: 1 second
Programmatic Pattern: GreaterP[0 Second]
BlankMassDetectionGains
For each member of Blanks, indicates the arbitrary-scaled signal amplification of the mass spectrometry measurement.
Format: Multiple
Class: Real
Programmatic Pattern: RangeP[0.01, 1000., 0.01]
BlankAbsorbanceSelection
For each member of Blanks, all the wavelengths of light absorbed in the detector's flow cell for a PhotoDiodeArray (PDA) detector.
Format: Multiple
Class: Expression
Programmatic Pattern: {GreaterP[0 Centimeter]..}
BlankMinAbsorbanceWavelengths
For each member of Blanks, the wavelength of light absorbed in the detector's flow cell for a PDA detector.
Format: Multiple
Class: Real
Unit: 1 nanometer
Programmatic Pattern: GreaterP[0 Centimeter]
BlankMaxAbsorbanceWavelengths
For each member of Blanks, the maximum wavelength of light absorbed in the detector's flow cell for a PDA detector.
Format: Multiple
Class: Real
Unit: 1 nanometer
Programmatic Pattern: GreaterP[0 Centimeter]
BlankWavelengthResolutions
For each member of Blanks, the increment in wavelength of light absorbed in the detector's flow cell for a PDA detector.
Format: Multiple
Class: Real
Unit: 1 nanometer
Programmatic Pattern: GreaterP[0 Centimeter]
BlankUVFilters
For each member of Blanks, indicates whether or not to block UV wavelengths (less than 210 nm) from being transmitted through the sample for Absorbance detectors (UVVis or PDA).
Format: Multiple
Class: Boolean
Programmatic Pattern: BooleanP
BlankAbsorbanceSamplingRates
For each member of Blanks, indicates the frequency of measurement for UVVis or PDA detectors.
Format: Multiple
Class: Real
Unit: 1 reciprocal second
Programmatic Pattern: 1
Hold[GreaterP[0 ------]]
Second
BlanksStorageConditions
For each member of Blanks, the storage conditions under which the blank samples should be stored after the protocol is completed.
Format: Multiple
Class: Expression
Programmatic Pattern: SampleStorageTypeP | Disposal
Column Flush
ColumnFlushGradientMethods
For each member of ColumnSelection, the composition of the CO2 and cosolvents within the flow, defined for specific time points during the washing of the columns (column flush).
Format: Multiple
Class: Link
Programmatic Pattern: _Link
Relation: Object[Method]
ColumnFlushCO2Gradient
For each member of ColumnSelection, the percentage of supercritical CO2 in the composition over time, in the form: {Time, % CO2} or a single % CO2 for each column flush run.
Format: Multiple
Class: Expression
Programmatic Pattern: {{GreaterEqualP[0 Minute], RangeP[0 Percent, 100 Percent]}...} | RangeP[0 Percent, 100 Percent]
ColumnFlushGradientA
For each member of ColumnSelection, the percentage of CosolventA in the composition over time, in the form: {Time, % Cosolvent A} or a single % Cosolvent A for each column flush run.
Format: Multiple
Class: Expression
Programmatic Pattern: {{GreaterEqualP[0 Minute], RangeP[0 Percent, 100 Percent]}...} | RangeP[0 Percent, 100 Percent]
ColumnFlushGradientB
For each member of ColumnSelection, the percentage of CosolventB in the composition over time, in the form: {Time, % Cosolvent B} or a single % Cosolvent B for each column flush run.
Format: Multiple
Class: Expression
Programmatic Pattern: {{GreaterEqualP[0 Minute], RangeP[0 Percent, 100 Percent]}...} | RangeP[0 Percent, 100 Percent]
ColumnFlushGradientC
For each member of ColumnSelection, the percentage of CosolventC in the composition over time, in the form: {Time, % Cosolvent C} or a single % Cosolvent C for each column flush run.
Format: Multiple
Class: Expression
Programmatic Pattern: {{GreaterEqualP[0 Minute], RangeP[0 Percent, 100 Percent]}...} | RangeP[0 Percent, 100 Percent]
ColumnFlushGradientD
For each member of ColumnSelection, the percentage of CosolventD in the composition over time, in the form: {Time, % Cosolvent D} or a single % Cosolvent D for each column flush run.
Format: Multiple
Class: Expression
Programmatic Pattern: {{GreaterEqualP[0 Minute], RangeP[0 Percent, 100 Percent]}...} | RangeP[0 Percent, 100 Percent]
ColumnFlushBackPressures
For each member of ColumnSelection, the applied pressure between the atmosphere and the PhotoDiodeArray detector exit, in the form: {Time, BackPressure} or a single BackPressure for each column flush run.
Format: Multiple
Class: Expression
Programmatic Pattern: {{GreaterEqualP[0 Minute], GreaterP[0 PSI]}...} | GreaterP[0 PSI]
ColumnFlushFlowRates
For each member of ColumnSelection, the total rate of mobile phase pumped through the instrument for each column flush.
Format: Multiple
Class: Expression
Programmatic Pattern: Milliliter 0 Milli Liter
Hold[ListableP[{GreaterEqualP[0 Minute], GreaterEqualP[0 ----------]}] | GreaterEqualP[-------------]]
Minute Minute
ColumnFlushTemperatures
For each member of ColumnSelection, the nominal temperature of the column compartment for each column flush run.
Format: Multiple
Class: Real
Unit: 1 degree Celsius
Programmatic Pattern: GreaterEqualP[0 Kelvin]
ColumnFlushIonModes
For each member of ColumnSelection, indicates if positively or negatively charged ions are analyzed each column flush run.
Format: Multiple
Class: Expression
Programmatic Pattern: IonModeP
ColumnFlushMakeupFlowRates
For each member of ColumnSelection, the total rate of MakeupSolvent pumped through the instrument for each column flush.
Format: Multiple
Class: Expression
Programmatic Pattern: Milliliter 0 Milli Liter
Hold[ListableP[{GreaterEqualP[0 Minute], GreaterEqualP[0 ----------]}] | GreaterEqualP[-------------]]
Minute Minute
ColumnFlushMassSelections
For each member of ColumnSelection, the all of the mass-to-charge ratio (m/z) measured via mass spectrometry.
Format: Multiple
Class: Expression
Programmatic Pattern: 0 Gram
Hold[{GreaterP[------]..}]
Mole
ColumnFlushMinMasses
For each member of ColumnSelection, the lowest measured mass-to-charge ratio (m/z) value.
Format: Multiple
Class: Real
Unit: 1 gram per mole
Programmatic Pattern: 0 Gram
Hold[GreaterEqualP[------]]
Mole
ColumnFlushMaxMasses
For each member of ColumnSelection, the highest measured mass-to-charge ratio (m/z) value.
Format: Multiple
Class: Real
Unit: 1 gram per mole
Programmatic Pattern: 0 Gram
Hold[GreaterP[------]]
Mole
ColumnFlushProbeTemperatures
For each member of ColumnSelection, the temperature of the needle that sprays column effluent into the ionization chamber for each ColumnFlush run.
Format: Multiple
Class: Real
Unit: 1 degree Celsius
Programmatic Pattern: GreaterP[0 Celsius]
ColumnFlushSourceTemperatures
For each member of ColumnSelection, the temperature that the source block is set to in order to discourage condensation and decrease solvent clustering in the reduced vacuum region of the source.
The source block is the metallic chamber with reduced pressure separating the sprayer (at atmospheric pressure) and the inside of the mass spectrometer (at 10^-7 Torr of pressure). It consists of the sampling cone, the isolation valve, and the ion block. The source temperature setting affects sensitivity.
Format: Multiple
Class: Real
Unit: 1 degree Celsius
Programmatic Pattern: GreaterP[0 Celsius]
ColumnFlushESICapillary Voltages
For each member of ColumnSelection, the applied voltage differential between the injector and the inlet plate for the mass spectrometry in order to ionize analyte molecules.
Format: Multiple
Class: Real
Unit: 1 volt
Programmatic Pattern: GreaterP[0 Volt]
ColumnFlushSamplingCone Voltages
For each member of ColumnSelection, the voltage offset between the 1st and 2nd stage of the stepwave ion guide which leads ions coming from the sample cone (the metal shield covering the front of the source block), towards the quadrupole mass analyzer.
Format: Multiple
Class: Real
Unit: 1 volt
Programmatic Pattern: GreaterP[0 Volt]
ColumnFlushScanTimes
For each member of ColumnSelection, the duration of time allowed to pass between each spectral acquisition.
Format: Multiple
Class: Real
Unit: 1 second
Programmatic Pattern: GreaterP[0 Second]
ColumnFlushMassDetectionGains
For each member of ColumnSelection, indicates the arbitrary-scaled signal amplification of the mass spectrometry measurement.
Format: Multiple
Class: Real
Programmatic Pattern: RangeP[0.01, 1000., 0.01]
ColumnFlushAbsorbance Selection
For each member of ColumnSelection, all the wavelengths of light absorbed in the detector's flow cell for a PhotoDiodeArray (PDA) detector.
Format: Multiple
Class: Expression
Programmatic Pattern: {GreaterP[0 Centimeter]..}
ColumnFlushMinAbsorbance Wavelengths
For each member of ColumnSelection, the wavelength of light absorbed in the detector's flow cell for a PDA detector.
Format: Multiple
Class: Real
Unit: 1 nanometer
Programmatic Pattern: GreaterP[0 Centimeter]
ColumnFlushMaxAbsorbance Wavelengths
For each member of ColumnSelection, the maximum wavelength of light absorbed in the detector's flow cell for a PDA detector.
Format: Multiple
Class: Real
Unit: 1 nanometer
Programmatic Pattern: GreaterP[0 Centimeter]
ColumnFlushWavelength Resolutions
For each member of ColumnSelection, the increment in wavelength of light absorbed in the detector's flow cell for a PDA detector.
Format: Multiple
Class: Real
Unit: 1 nanometer
Programmatic Pattern: GreaterP[0 Centimeter]
ColumnFlushUVFilters
For each member of ColumnSelection, indicates whether or not to block UV wavelengths (less than 210 nm) from being transmitted through the sample for PDA detector.
Format: Multiple
Class: Boolean
Programmatic Pattern: BooleanP
ColumnFlushAbsorbanceSampling Rates
For each member of ColumnSelection, indicates the frequency of measurement for UVVis or PDA detectors.
Format: Multiple
Class: Real
Unit: 1 reciprocal second
Programmatic Pattern: 1
Hold[GreaterP[0 ------]]
Second
Last modified on Mon 26 Sep 2022 15:43:51